Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons

O. Yañez, A. Vásquez-Espinal, R. Pino-Rios, F. Ferraro, S. Pan, E. Osorio, G. Merino, W. Tiznado

Resultado de la investigación: Contribución a una revistaArtículo

18 Citas (Scopus)

Resumen

A new approach to stabilize compounds containing a planar tetracoordinate carbon (ptC), embedded in aromatic hydrocarbons, is presented herein. This is achieved by using ligands that promote the formation of a 3c-2e σ-bond with the ptC under two conditions: without altering the sp2 hybridization of the aromatic carbons; and containing empty orbitals perpendicular to the aromatic ring to participate in the aromatic π-electronic delocalization.

Idioma originalInglés
Páginas (desde-hasta)12112-12115
Número de páginas4
PublicaciónChemical Communications
Volumen53
N.º89
DOI
EstadoPublicada - 1 ene 2017

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  • Citar esto

    Yañez, O., Vásquez-Espinal, A., Pino-Rios, R., Ferraro, F., Pan, S., Osorio, E., Merino, G., & Tiznado, W. (2017). Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons. Chemical Communications, 53(89), 12112-12115. https://doi.org/10.1039/c7cc06248f